Microlatex hair cosmetic composition

ABSTRACT

Novel hair cosmetic compositions comprising from 0.01 to 10% by weight of a particulate polymer having a weight average diameter of from 0.005 to 0.2 μm, said particulate polymer has a particle size distribution of such that the particles ranging from 0.005 to 0.2 μm in diameter are contained over 95% by weight and has a glass transition temperature, Tg, of over 300° K. As the particulate polymer, polymer latex such as polystyrene latex, vinyl homopolymer latex, polyurethane latex, epoxy resin latex and the like are preferably used. 
     The hair cosmetic compositions provide excellent hair style-forming/retaining property, good combing performance and good feeling of the treated hair. Further, they are free from easy separation which is inevitable for conventional compositions containing inorganic powder such as talc, mica and titanium.

This is a division of application Ser. No. 902,651, filed Sept. 2, 1986,now U.S. Pat. No. 4,798,721.

BACKGROUND OF THE INVENTION

1. Field of the Invention

This invention concerns hair cosmetic compositions and more specificallysuch compositions containing a water-insoluble fine particulate polymer,having excellent style-forming or retaining performance of hair andfurther giving a favorable feeling to touch to the hair. 2. Descriptionof the Prior Art

Hair style is one of most important factors in beauty cares, and variouskinds of beauty treatments have been prevailed for making the style. Forinstance, hair may be wound and dried around curlers, or treated by adrier and brushes to make a style. In such hair cares, it is a usualpractice that hair cosmetics such as set lotions, blowing agents, hairsprays and the like are used for the purpose of facilitating a stylemaking or retaining the thus prepared hair style. Hair cosmeticcompositions, therefore, are incorporated with polymers which aresoluble in water or in organic solvents such as alcohols Examples ofsuch polymers are polyvinyl pyrrolidone, vinyl pyrrolidone/vinyl acetatecopolymer, vinylpyrrolidone/vinyl acetate/alkylamino acrylate copolymer,methylvinyl ether/maleic anhydride copolymer, vinylacetate/chrotonicacid copolymer, copolymer of acrylic or methacrylic acid and acrylic ormethacrylic acid esters. Hair styles have been formed or retained by thepolymers spread or applied by way of aerosol to the hair.

However, conventional hair cosmetic compositions have disadvantages inthat they necessitate a great amount of polymer materials to bedeposited on the hair in order to retain the hair style. In addition,since the polymer materials deposited on the hair have a surface tensionhigher than the critical surface tension of the hair, they are depositedin the island-like small lumps on the hair, which leads to the stifffeeling of the hair and insufficient combing performance.

Hair rinses, hair treatment agents, etc. have been used aftercontaminations on the hair are removed by a shampoo in order toeliminate the unfavorable driness of the hair, to impart a soft touch tothe hair and to obtain a smooth combing. However, since they containcationic surface active agents or oily ingredients, although they canimprove the softness and combing property of the hair, they areaccompanied by drawbacks in that the hair becomes sticky and hair stylesare difficult to be made or retained, thus improvement has been demandedtherefor.

SUMMARY OF THE INVENTION

In view of the foregoing situations, the present inventors have made anearnest study for obtaining a hair cosmetic composition having anexcellent hair style forming or retaining performance and, as a result,have accomplished this invention based on the finding that hair cosmeticcomposition capable of providing hair with an excellent style-forming orretaining effect without impairing the feelings of the hair andexhibiting favorable combing property can be obtained by blending aparticular polymer with hair cosmetic compositions for shampoos, rinses,treatments, hair sprays, set lotions and the like.

Accordingly, this invention provides hair cosmetic compositionscomprising from 0.01 to 10% by weight of a particulate polymer having aweight average diameter of from 0.005 to 0.2 μm, said particulatepolymer has a particle size distribution of such that the particlesranging from 0.005 to 0.2 μm in diameter are contained over 95% byweight and has a glass transition temperature, Tg, of over 300° K. It ispreferred that the particulate polymer having the particle size asdescribed above is used in the form of a polymer latex comprising thatparticulate polymer.

DETAILED DESCRIPTION OF THE INVENTION AND PREFERRED EMBODIMENTS

The polymer latex comprising the particulate polymer cannot be preparedby a conventional emulsion polymerizing process in that a polymerizationis carried out in the presence of the emulsion of droplets ofpolymerizable monomers in the polymerization system.

According to this invention, the polymer latex is prepared bypolymerizing a water-insoluble polymerizable monomer in a microemulsionor solubilized state. The microemulsion can be prepared by using anonionic surface active agent and selecting a temperature appropriatelynear the phase transition temperature, or by combining the anionicsurface active agent with an appropriate auxiliary surface active agentsuch as a higher alcohol or nonionic surface active agent. Further, thesolubilized state can be obtained by using a great amount of a surfaceactive agent relative to the polymerizable monomer.

Among them, most preferred is a process of conducting a polymerizationin the state of the microemulsion using a nonionic surface active agent,setting the polymerizing temperature near the phase transitiontemperature and the interfacial tension between the monomer and water tonot more than 1 dyne/cm and, preferably, not more than 0.5 dyne/cm.

The process for preparing the polymer latex used in the invention willbe explained together with polymerizable monomers usable for thepreparation.

(1) Addition-polymerized polymer latex:

Addition-polymerized latex can be obtained by polymerizing apolymerizable monomer while maintaining the microemulsion of an aqueoussolution of a surface active agent having an interfacial tension betweenthe monomer and water of less than 1 dyne/cm, in which the polymerizablemonomer is solubilized within micelles formed by the surface activeagent.

As the polymerizable monomer, any of known monomers usable in theemulsion polymerization can be used, which include ethylene unsaturatedmonomers such as ethylene, propylene, isobutene and butene-1; aromaticvinyl monomers such as styrene, α-methylstyrene, vinyl toluene,halogenated styrene and divinyl benzene; acrylic esters having from 1 to20 carbon atoms in the alkyl group such as ethyl acrylate, butylacrylate and 2-ethylhexyl acrylate; methacrylate having from 1 to 20carbon atoms such as methyl methacrylate, butyl methacrylate and laurylmethacrylate; vinyl esters such as vinyl acetate and vinyl propionate;vinyl ethers having from 1 to 20 carbon atoms such as ethyl vinyl etherand butyl vinyl ether; vinyl ketones having from 1 to 20 carbon atomssuch as methyl vinyl ketone and ethyl vinyl ketone; vinyl cyan monomerssuch as acrylonitrile and methacrylonitrile; halogenated vinyls andhalogenated vinylidene such as vinyl chloride, vinyl bromide, vinylidenechloride and vinylidene bromide; and conjugated aliphatic dienes such as1,3-butadiene and 2-methyl-1,3-butadiene. These monomers can be usedsolely or as a mixture of two or more of them. Further, any of theabove-mentioned monomers can be subject to copolymerization with maleicanhydride, a water soluble monomer, styrene sulfonic acid (salt), vinylnaphthalene sulfonic acid (salt) or acrylic acid (salt).

The most preferred process for producing the addition polymerized latexis carried out by adding a surface active agent in a reaction vesselcharged with water to prepare an aqueous solution, adding polymerizablemonomers and, if required, an aqueous solution of a radicalpolymerization initiator thereto while stirring under heat near thetemperature at which the micelles of the surface active agent cause thephase transition while maintaining such a state as the interface tensionbetween the monomer and water is not more than 1 dyne/cm, preferablyfrom 0 to 0.5 dyne/cm, thereby initiating polymerization and thengradually adding a polymerizable monomer such that the interfacialtension between the aqueous solution of the surface active agent and themonomer phase does not exceed the above-mentioned range.

The radical polymerization initiator suitably used herein can include,for example, persulfates such as potassium persulfate, sodium persulfateand ammonium persulfate; azo compounds such as mineral acid salt of2,2'-azobis(2-amidino propane), azobis-cyanobuareric acid and alkalimetal or ammonium salt thereof; and redox type initiators such astartaric acid-hydrogen peroxide, Rongalit-peroxide and ascorbicacid-peroxide. Among them, 2,2'-azobis(2-amidino propane) mineral acidsalt is used preferably in the case of using the cationic surface activeagent in the polymerization system and the persulfate is suitably usedin other polymerization systems. The amount of the radicalpolymerization initiator is from 0.1 to 5 parts by weight and,preferably, from 0.1 to 3 parts by weight based on 100 parts by weightof the monomer constituting the polymer.

The reaction temperature is the highest temperature within thesolubilizing region near the phase transition temperature, and atemperature within a range from 50° to 90° C. is preferred. While thetime required for the polymerization varies depending on the type,composition and the concentration of the monomer, or the concentrationof the radical polymerization initiator, polymerizing temperature, etc.,the range from 5 to 50 hours is preferred.

In this way, a polymer latex containing a particulate polymer having anaverage particle size from 0.005 to 0.2 μm and in which 95% by weight ormore of the particles have such a particle size range is obtained.

(2) Polycondensation latex:

Polycondensation latex is obtainable by polymerizing a polycondensablemonomer while maintaining the microemulsion of an aqueous solution of asurface active agent, which has an interfacial tension between themonomer and water of not more than 1 dyne/cm, and in which thepolycondensable monomer is solubilized within the micelles formed by thesurface active agent.

As the polycondensable monomer, any of known monomers usable in theinterface polycondensation or low temperature polycondensation can beused. Among them, those monomers capable of forming polyamides orpolyesters are preferred. For instance, the acid component for preparingthe polyamide includes alkylene dicarboxylic acids comprisinghydrocarbons having from 1 to 24 carbon atoms, phthalic acid such asdimeric acid, terephthalic acid and isophthalic acid, corresponding acidchlorides or acid anhydrides of aromatic polybasic carboxylic acids andcycloaliphatic polybasic carboxylic acids such as cyclohexyldicarboxylic acid and, further, thioesters of dicarboxylic acids.Further, the amine component can include, for example, aliphaticpolyamines comprising hydrocarbons of from 1 to 24 carbon atoms, forexample, alkylene diamine and alkylene triamine, aromatic polyamidessuch as phenylene diamine and polyamines having heterocyclic ring suchas 4,4'-diaminophenyl ether.

Further, the alcohol component in the case of preparing the polyesterincludes alkylene diols comprising hydrocarbons with from 1 to 24 carbonatoms, ethylene glycol condensate such as bis-β-hydroxyethylterephthalate, aromatic polyhydric alcohols such as hydroquinone andbisphenol A, polyhydric alcohols such as glycerine derivatives. As theacid component, various compounds as described above can be mentioned.

The monomers are not restricted only to those as described above, andtwo or more of the monomers may further be used in admixture.

For practicing the polycondensation reaction, a surface active agent isadded to a reactor charged with water for solubilizing the acidcomponent by agitation. Thereafter, an aqueous solution of diamine oralcohol is added, or alternatively, solutions prepared by dissolvingboth of the components separately in organic solvents are solubilized inthe respective aqueous solutions of the surface active agent and mixed.A solid monomer is preferably dissolved in an organic solvent andsolubilized together with the solvent in micelles for conducting thepolycondensation. In this case, any of water-insoluble solvents may beused and benzene, toluene, xylene or the like is preferably used Thereaction temperature is preferably at a temperature within thesolubilizing region near the phase transition temperature and,generally, from -10° to 50° C. Further, while the reaction time variesdepending on the type, composition and the concentratin of the monomeror the temperature, 2-60 minutes of time is usually preferred.

In this way, a polymer latex containing a particulate polymer having anaverage particle diameter from 0.005 to 0.2,μm, in which 95% or more ofthe particles have a diameter falled within this range can be obtained.

(3) Polyaddition polymerized latex:

The polymer latex of polyaddition polymer is obtainable by polymerizinga monomer capable of polycondensation in a state where the monomercapable of polycondensation is solubilized in a plate-like micellesformed with the surface active agent, while using an aqueous solution ofa surface active agent providing the interfacial tension between themonomer and water of not more than 0.5 dyne/cm and while maintaining thestate of the microemulsion.

While all of known monomers usable in the ordinary polyaddition reactioncan be used as the monomer capable of polyaddition, those monomersdirected to polyurethanes, polyurea resins and epoxy resins arepreferred.

The alcohol component for preparing the polyurethane includes thosecompounds having at least two hydroxy groups in one molecule,specifically, ethylene glycol, propylene glycol, butylene glycol,hexanediol, neopentyl glycol, polyethylene glycol, polypropylene glycol,polyoxytetramethylene glycol, glycerine, trimethylol propane andpolyester having two or more terminal hydroxyl groups. Further, theisocyanate component includes those compounds having at least twoisocyanate groups in one molecule, specifically, tolylene diisocyanate,xylylene diisocyanate, hexamethylene diisocyanate, 4,4'-diphenylmethanediisocyanate, triphenylmethane triisocyanate, trimethylol propanetriisocyanate, polyesters, polyethers and polyurethanes having two ormore terminal isocyanate groups.

The above-mentioned compounds can be used as the isocyanate componentfor producing polyurea, and the amine compounds includes those compoundshaving at least two amino groups in one molecule, specifically,hexamethylene diamine, dodecyldiamine, phenylene diamine,diaminodiphenyl ether and piperazine.

The epoxy component for preparing the epoxy resin includes thosecompounds having at least two epoxy groups in one molecule,specifically, diglycidyl ether compound of bisphenol A, glycidyl estercompound of dimeric acid and compounds prepared by oxidizing olefins.Further, the amine compounds as described above can be used as the aminecomponent. Further, all of known hardners can be used, for example,tertiary amines, boron trifluoride-amine complex and imidazole, as wellas amines, polyamines, carboxylic acid anhydrides, polysulfides,dicyandiamides and diisocyanates having functional groups capable ofpolyaddition reaction with the epoxy groups.

The polyaddition reaction is carried out as follows. In order to preparethe polyurethane or polyurea, a surface active agent is added to areactor vessel charged with water thereby solubilizing the isocyanateingredient under stirring. Next, an aqueous solution of diol or diamineis added thereto, or alternatively solutions of both of the ingredientsdissolved separately in an organic solvent are solubilized in theaqueous solutions of the surface active agent and mixed the two. Inorder to prepare the epoxy resin, a solution of a prepolymer or acombination of terminal epoxy compound and various hardners dissolved ina solvent is added dropwise to the heated aqueous solution of thesurface active agent.

In the case where the monomer is solid or highly viscous liquid, it ispreferred to first dissolve the monomer in an organic solvent beforecarrying out the polyaddition reaction in micelles. Any of inertsolvents insoluble in water and not reactive with any of the ingredientsmay be used as the organic solvent, and benzene, toluene, xylene, etc.are particularly preferred. The reaction temperature is selected withina solubilizing region near the phase transition temperature and,usually, it is preferably from 20° to 70° C. Further, while the reactiontime varies depending on the kind, composition and the concentration ofthe monomer, or the temperature etc., it is preferably from 1 to 50hours.

The phenol resin which is a polycondensate can be prepared in the samemanner as employed for the epoxy resin described above. It can beprepared by using phenol derivative such as phenol or cresol andformaldehyde. In addition, a resol resin or novolak resin may be used,which is hardened by acid or polyamine.

The latex thus obtained contains particulate polymer having an averageparticle size from 0.005 to 0.2 μm and 95% by weight or greater of theparticles have a particle size within the above-mentioned range. Theaverage particle size of the polymer used in this invention is from0.005 to 0.2 μm and, more preferably, from 0.01 to 0.1 μm converted fromthe weight value. Further, 95% by weight or greater of the polymerparticles have the particle size within the range from 0.005 to 0.2 μm.When the polymer is incorporated into hair cosmetic compositions, thedepositing property to the hair is degraded and no substantial effectfor style-forming or retaining effect can be recognized if the particlesize is too large or too small. Accordingly, those latexes used as aclouding agent to cream shampoos or the like cannot produce the effectof this invention because their average particle size is greater than0.2 μm and they have a broader range of the particle size distribution.

The polymer used in this invention has a glass transition temperature(Tg) of higher than 300° K. If the glass transition temperature is lowerthan the above-mentioned value, the latex shows poorstyle-forming/retaining effect if it should deposit to the hair. Thepolymers having glass transition temperature (Tg) of higher than 300° K.include polymers of vinyl monomers such as polystyrene, polyvinylacetate, polydivinyl benzene, polymethyl methacrylate; polyamides suchas 6,12-nylon; polyurethanes such as polyaddition polymer ofpolypropylene glycol (average molecular weight of 1000) and xylenediisocyanate; and epoxy resins such as polyaddition polymer of bisphenolA and diglycidyl ether The vinyl monomers can be added with othermonomers in such an extent as not rendering the glass transitiontemperature (Tg) below 300° K.

Among the polymers, most preferred are those polystyrenes and copolymersof styrene and a vinyl monomer other than styrene that have glasstransition temperature (Tg) of higher than 300° K.

The hair cosmetic compositions according to this invention are preparedby blending the polymer obtained as described above directly with asubstrate material of the hair cosmetic compositions, or by blending aliquid suspension of the polymer previously concentrated to a desiredconcentration with the substrate. In the case of the preparation ofaqueous hair cosmetic compositions, it is preferred to add the polymerto water before blending with other ingredients such as a thickner. Thepolymer is preferably blended into the hair cosmetic compositions withina range from 0.01 to 10% by weight and, more preferably, from 0.05 to 5%by weight calculated as the residue after water is removed.

Further, a long-chain alkyl quaternary ammonium salt and oils and fatscan be incorporated into the hair cosmetic composition according to thisinvention in order to provide the hair with more favorable feelings. Thelong-chain alkyl quaternary ammonium salt can include those long-chainalkyl quaternary ammonium salts represented by the following generalformula (I): ##STR1## wherein one or two of R₁ - R₄ represent a linearor branched long chain alkyl group having 8 to 24 carbon atoms and theremaining portion thereof represent alkyl or hydroxy alkyl group having1 to 3 carbon atoms or benzyl group and X represents a halogen atom oran alkyl sulfate group having 1 or 2 carbon atoms, and they may be usedalone or in admixture of two or more of them. Among the long chain alkylquaternary ammonium salts represented by the foregoing formula (I),those having branched long chain alkyl groups may be synthesized by aknown method starting from a branched higher fatty acid or branchedhigher alcohol This starting materials may be of natural or syntheticproducts. The natural starting material can include lanolin fatty acidssuch as iso acid and anti-iso acid and terpene alcohols such asfarnesol. The synthetic starting material can include oxoalcoholprepared by the oxo process, or Guerbet alcohol or 2-alkyl alkanolobtained through Guerbet condensation or aldol condensation startingfrom alcohol or aldehyde. For instance, in the case of oxo alcohol, therate of branching compound of the resultant higher alcohol is small whenstarting from α-olefin, the rate of branching compound is increased inthe case of the internal olefin and the rate of branching compound isincreased to 100% in the case of branched olefin.

Among the branched type long chain alkyl quaternary ammonium salts,preferred are those having, as the branched alkyl group, 2-methylalkylgroup represented by the following general formula (II): ##STR2##wherein R represents a linear alkyl group having 5 to 13 carbon atomsand preferred examples of the group include 2-methyloctyl,2-methyldecyl, 2-methylundecyl, 2methyldodecyl, 2-methyltridecyl,2-methyltetradecyl 2methylheptadecyl, etc. These 2-methyl alkyl groupsare usually derived from oxo alcohol which is generally obtained as amixture of linear-chain alcohols.

Those branched type long chain alkyl quaternary ammonium salts havingthese branched alkyl groups include alkyltrimethyl ammonium chloride,dialkyldimetyl ammonium chloride, alkyldimethyl benzyl ammoniumchloride, alkyltrimethyl ammonium bromide, alkyltrimethyl ammoniummethosulfate and dialkylmethyl hydroxymethyl chloride Among them,particularly preferred are those having the 2-methylalkyl grouprepresented by the formula (II), which examples are branched long chainmonoalkyl quaternary ammonium salt such as 2-methyldecyltrimethylammonium chloride, 2-methyldodecyltrimethyl ammonium chloride,2-methyltetradecyltrimethyl ammonium chloride; branched long chaindialkyl quaternary ammonium salt in which one of the long chain alkylgroup is branched such as 2-methyldecylundecyldimethyl ammoniumchloride, 2-methyldodecyltridecyldimethyl ammonium chloride,2-methyltetradecylpentadecyldimethyl ammonium chloride; and branchedlong chain dialkyl ammonium salts in which both of the long chain alkylgroups are branched such as di(2-methyldecyl)dimethyl ammonium chloride,di(2-methyldodecyl)dimethyl ammonium chloride and di(2-methyltetradecyl)dimethyl ammonium chloride.

Further, examples of linear long chain alkyl groups can include, decyl,undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl,octadecyl, eicosanyl group and the like.

Those oils and fats generally employed can be used and they includeliquid paraffins, glycerides, higher alcohols, lanolin derivatives,esters and higher fatty acid. Glycerides used are those mono-glyceridefatty acids derived from saturated or unsaturated linear or branchedchains having from 12 to 24 carbon atoms. Among the oils and fats, thosehigher alcohols having linear or branched alkyl or alkenyl groups having12 to 26 carbon atoms are particularly preferred and specific examplesthereof include cetyl alcohol, stearyl alcohol, arachidic alcohol,behenyl alcohol, carnaubyl alcohol and ceryl alcohol.

The long chain alkyl quaternary ammonium salts and oils and fats arepreferably incorporated within a range from 0.01 to 20% and from 0.1 to30%, respectively.

When 0.01 to 10 wt% of casein or a casein derivative is incorporatedinto a hair cosmetic composition of the present invention, the hairstyle forming/retaining effect is further enhanced without impeding feelto the touch of the hair. The casein derivatives include metal salts ofcasein, hydrolysates of casein and the like. A sodium salt and ahydrolysate having an average molecular weight of 1,000 to 50,000 arepreferable as the metal salt of casein and the hydrolysate of casein,respectively.

The hair cosmetic compositions that can provide excellent effects due tothe incorporation of the polymer and, if required, long chain alkylquaternary ammonium salt and oils and fats in this invention have noparticular restriction and they can include, for example, shampoos, hairrinses, hair conditioners, hair treatments, blowers, hair settingagents, hair liquids, hairtonics, brushing agents, hair sprays and haircolors. Further, there are no particular restrictions for theformulations of hair cosmetic compositions that can be blended with thepolymer and they can include, for example, an aqueous solution, ethanolsolution, emulsion, suspension, gel, solid-form, aerosol, powder and thelike.

The hair cosmetic compositions according to this invention are excellentin the style-forming/retaining effect, depositing property, feeling, andcan impart excellent style-forming/retaining ability and favorable touchto the hair. Further, they are free from the drawbacks such as easyseparation and poor combing, when incorporated in a hair cosmeticcomposition, as compared with inorganic powder such as talc, mica andtitanium easily available as a fine powder.

This invention will now be explained referring to Synthesis Examples andExamples.

Synthesis Examples

Latexes were prepared by the Methods 1-8 shown below and the averageparticle size and the glass transition temperature Tg were determinedand shown in Table 1. The average particle size was measured by asub-micron particle analyzer "Coultar Model N-4" and represented by theaverage weight value. Tg was determined according to Polymer Handbook (AWiley-Interscience Publication, John Wiley & Sons Inc., 1975).

Method 1

Polystyrene Latex A:

A separable flask made of glass and equipped with a stirrer was chargedwith 500 parts by weight (hereinafter referred to simply as parts) ofdistilled water, 25 parts of polyoxyethylene (30) nonylphenyl ether(numeral value in the parenthesis represents here and hereinafter theaverage number of addition mol of ethylene oxide) and 1.2 parts ofammonium persulfate. The flask was purged with nitrogen to remove allair and heated to 62° C. while stirring. 125 parts of styrene weredropped over 2 hours and polymerization was proceeded for further 6hours to obtain polystyrene latex A.

Method 2

Polystyrene Latex B:

A separable flask made of glass and equipped with a stirrer was chargedwith 500 parts of distilled water, 15 parts of polyoxyethylene(30)nonylphenyl ether, 0.5 parts of ammonium persulfate and 0.5 parts ofsodium sulfite. The flask was purged with nitrogen to remove all air andheated to 45° C. while stirring. 50 parts of styrene were dropped overone hour and polymerization was proceeded for further 8 hours to obtainpolystyrene latex B.

Method 3

Polystyrene Latex C:

Polystyrene latex C was prepared in the same manner as in the Method 2excepting for lowering the reaction temperature to 35° C.

Method 4

Vinyl Homopolymer Latex:

Various kinds of vinyl homopolymer latexes were obtained by usingpolyoxyethylene(30) nonylphenyl ether as the surface active agent, vinylacetate monomer, methyl methacrylate monomer, n-butyl acrylate monomer,n-butyl methacrylate monomer or 2-ethylhexyl methacrylate monomer as themonomer and in the same manner as in the Method 1.

Method 5

Nylon Latex:

In each of two beakers, 13 parts of polyoxyethylene(30) nonylphenylether and 200 parts of water were charged and stirred. A solution of 2parts of dodecyldiamine dissolved in toluene was added to one (solutionA) of the thus obtained aqueous solutions, while 1.8 parts of adipicdichloride was added to another solution (solution B) and they werestirred respectively. Both of the thus obtained transparent solubilizedsolutions were mixed under stirring at a room temperature and, afteradjusting the pH to about 10 by using 5N-NaOH, reacted for several hoursto obtain 6,12-nylon latex.

Method 6

Polyurethane Latex:

In each of two beakers, 13 parts of polyoxyethylene(30) nonylphenylether and 200 parts of water were charged and stirred. A solution of 25parts of polypropylene glycol (average molecular weight 1000) dissolvedin toluene was added to one (solution A) of the thus obtained aqueoussolution, while 5 parts of xylylene diisocyanate was added to anothersolution (solution B) and they were stirred respectively. After mixingthese two solutions at room temperature, the mixed solution was stirredfor two hours to obtain polyurethane latex.

Method 7

Epoxy Resin Latex:

An aqueous solution containing 12 parts of polyoxyethylene(30)nonylphenyl ether dissolved in 200 parts of water was heated to 60° C.,to which was added a solution of 2 parts of diglycidyl ether ofbisphenol A dissolved in 8 parts of toluene, followed by stirring. 0.3parts of dodecyl diamine was further added to the solubilized solutionand reacted for further 4 hours at the same temperature to obtain anepoxy resin latex.

Method 8

Styrene Copolymer Latex:

A styrene copolymer latex was obtained by the method according to thepreparation process for the polystyrene latex shown in the Method 1 byusing the same polyoxyethylene(30) nonylphenyl ether as the surfaceactive agent, and replacing styrene with a mixture of styrene andvarious kinds of monomers (vinyl acetate monomer, sodium styrenesulfonate monomer, trimethylaminoethyl methacrylate chloride monomer).

The glass transition temperature, the average particle size and theratio of particles having the particle size from 0.005 to 0.2 μm for thelatexes obtained in the Methods 1-8 of the Synthesis Examples arecollectively shown in Table 1.

EXAMPLE 1

A hair treatment composition was prepared by adding water to each of thepolymer latexes obtained in the Methods 1-8 of the Synthesis Examples soas to have 1% by weight of the polymer material. Each composition wasthen tested for the following items and the results are shown in Table2. Further, a hair rinse composition comprising 2% by weight of stearyltrimethyl ammonium chloride, 2% by weight of cetanol, 1% by weight ofpolymer latex (polymer content) and the balance of water was prepared,the performance was evaluated in the same manner. The results are shownin Table 3.

(1) Combing Force

20 g of human hair was wetted with water at 40° C. to be impregnatedwith 10 g of water content. The hair was treated for 30 sec. by using 2g of a test solution shown in Table 2 and then rinsed for 30 sec. inrunning water at 40° C. After draining, the hair was dried by a dryer,left for one night in a thermostable and humidity stable chamber at 20°C. and 65% RH, set to a strain gage and then applied with combing inwhich a force exerted on the comb was measured.

(2) Style-Forming/Retaining Effect

A bundle of hair weighing 5 g and 20 cm long was treated for one minutewith each of the test solutions shown in Table 2, rinsed and then woundaround a glass tube of 1 cm diameter. Then the hair was left for onenight in a thermostable and humidity stable chamber at 20° C. and 65RH%, air dried and detached from the glass tube and then the length ofthe curl was measured with the elapse of time. The curl retainabilitywas calculated from the result by using the following equation and thestyle-forming/retaining effect was examined by the following evaluationcriteria. ##EQU1## L_(O) : 20 cm L_(A) : Curl length (cm) just afterdetaching from the glass tube.

L_(B) : Curl length 12 hours after detaching from the glass tube.

    ______________________________________                                        Style-forming/retaining effect                                                                    Curl retainability (%)                                    ______________________________________                                        O                   between 65 and 100                                        Δ             between 50 and 65                                         X                   between 0 and 50                                          ______________________________________                                    

(3) Depositing Property to Hair

Hair of 20 cm long and 50 μm in diameter was treated and dried in thesame manner as described in (1) above. The hair was observed under ascanning electron microscope and the state of the fine polymer particlesdeposited to the surface of the hair was evaluated by the followingevaluation criteria.

Evaluation criteria:

    ______________________________________                                        Deposition                                                                    property     State on the Hair Surface                                        ______________________________________                                        A            Deposits found substantially over the                                         entire surface                                                   B            Deposits found partially                                         C            Deposits found slightly                                          D            No deposits found at all                                         ______________________________________                                    

(4) Feeling

A bundle of Japanese virgin hair was treated by the test solutions shownin Table 2 by the method as described in (1) above and then air-dried.The bundle of hair was evaluated for the feeling at five steps by 20female members. The criterion for the evaluation was given as good(score 5), rather good (score 3), ordinary (score 3), somewhat poor(score 2) and poor (score 1) and the results were expressed as thegeometrical mean.

                                      TABLE 1                                     __________________________________________________________________________                                       Glass                                                                    Synthesis                                                                          transition                                                                          Average particle                                                                       Particles having                                                              particle                    Polymer latex                 method                                                                             temp (°K)                                                                    size (μm)                                                                           size of 0.005-0.2 μm                                                       (wt %)                      __________________________________________________________________________    A.                                                                              Polystyrene A               Method 1                                                                           373   0.066 ± 0.008                                                                       100                         B.                                                                              Polystyrene B               Method 2                                                                           373   1.2 ± 0.1                                                                            0                          C.                                                                              Polystyrene C               Method 3                                                                           373   2.0 ± 0.5                                                                            0                          D.                                                                              Polyvinyl acetate           Method 4                                                                           305   0.058 ± 0.008                                                                       100                         E.                                                                              Polydivinyl benzene         Method 4                                                                           379   0.078 ± 0.007                                                                       100                         F.                                                                              Polymethyl methacrylate     Method 4                                                                           378   0.063 ± 0.004                                                                       100                         G.                                                                              Poly-n-butyl acrylate       Method 4                                                                           219   0.12 ± 0.01                                                                          98                         H.                                                                              Poly-n-butyl methacrylate   Method 4                                                                           293   0.075 ± 0.004                                                                       100                         I.                                                                              Poly-2-ethylhexyl methacrylate                                                                            Method 4                                                                           263   0.15 ± 0.02                                                                          96                         J.                                                                              6,12-nylon                  Method 5                                                                           319   0.035 ± 0.005                                                                       100                         K.                                                                              Polyurethane                Method 6                                                                           379   0.055 ± 0.006                                                                       100                         L.                                                                              Epoxy resin                 Method 7                                                                           393   0.047 ± 0.005                                                                       100                         M.                                                                              Styrene/vinyl acetate (99/1) copolymer                                                                    Method 8                                                                           372   0.052 ± 0.003                                                                       100                         N.                                                                              Styrene/sodium styrene sulfonate (94/6) copolymer                                                         Method 8                                                                           363   0.042 ± 0.005                                                                       100                         O.                                                                              Styrene/trimethyaminoethyl methacrylate chloride                                                          Method 8                                                                           358   0.096 ± 0.007                                                                       100                           (94/6) copolymer                                                            P.                                                                              Sytrene/vinyl acetate copolymer (commercial goods)                                                        --   --    0.2 ± 0.1                                                                            50                         Q.                                                                              Styrene/vinyl pyrrolidone copolymer (commercial goods)                                                    --   --    0.5 ± 0.3                                                                            30                         R.                                                                              Nylon (commercial goods)    --   --    2.0 ± 0.5                                                                            0                          __________________________________________________________________________

                                      TABLE 2                                     __________________________________________________________________________                                       Style-forming                                                                             Feeling of                                                   Combing                                                                            retaining                                                                            Hair treated                        Polymer latex                 force (g)                                                                          effect depositon                                                                          hairs                          __________________________________________________________________________    A.                                                                              Polystyrene A               200  O      A    3.0                            B.                                                                              Polystyrene B               265  X      C    1.2                            C.                                                                              Polystyrene C               220  X      C    2.0                            D.                                                                              Polyvinyl acetate           208  O      A    3.2                            E.                                                                              Polydivinyl benzene         207  O      A    2.6                            F.                                                                              Polymethyl methacrylate     205  O      A    2.7                            G.                                                                              Poly-n-butyl acrylate       210  Δ                                                                              A    1.8                            H.                                                                              Poly-n-butyl methacrylate   212  Δ                                                                              A    2.0                            I.                                                                              Poly-2-ethylhexyl methacrylate                                                                            210  Δ                                                                              A    2.3                            J.                                                                              6,12-nylon                  165  O      A    3.7                            K.                                                                              Polyurethane                178  O      A    3.5                            L.                                                                              Epoxy resin                 210  O      A    2.5                            M.                                                                              Styrene/vinyl acetate (99/1) copolymer                                                                    203  O      A    3.0                            N.                                                                              Styrene/sodium styrene sulfonate (94/6) copolymer                                                         196  O      A    2.4                            O.                                                                              Styrene/trimethyaminoethyl methacrylate chloride                                                          210  O      A    2.4                              (94/6) copolymer                                                            P.                                                                              Sytrene/vinyl acetate copolymer (commercial goods)                                                        243  X      C    2.0                            Q.                                                                              Styrene/vinyl pyrrolidone copolymer (commercial goods)                                                    238  X      C    2.4                            R.                                                                              Nylon (commercial goods)    220  X      C    2.2                            S.                                                                              None (control)              200  X      D    1.2                            __________________________________________________________________________

                                      TABLE 3                                     __________________________________________________________________________                                       Style-forming                                                                             Feeling of                                                   Combing                                                                            retaining                                                                            Hair treated                        Polymer latex                 force (g)                                                                          effect depositon                                                                          hairs                          __________________________________________________________________________    A.                                                                              Polystyrene A                96  O      A    4.5                            B.                                                                              Polystyrene B               118  X      C    2.5                            C.                                                                              Polystyrene C               100  X      C    4.0                            D.                                                                              Polyvinyl acetate           105  O      A    4.2                            E.                                                                              Polydivinyl benzene          97  O      A    3.7                            F.                                                                              Polymethyl methacrylate      97  O      A    4.0                            G.                                                                              Poly-n-butyl acrylate        93  Δ                                                                              A    3.0                            H.                                                                              Poly-n-butyl methacrylate    95  Δ                                                                              A    3.1                            I.                                                                              Poly-2-ethylhexyl methacrylate                                                                             97  Δ                                                                              A    2.9                            J.                                                                              6,12-nylon                   90  O      A    4.5                            K.                                                                              Polyurethane                 92  O      A    4.5                            L.                                                                              Epoxy resin                 103  O      A    3.8                            M.                                                                              Styrene/vinyl acetate (99/1) copolymer                                                                     92  O      A    4.6                            N.                                                                              Styrene/sodium styrene sulfonate (94/6) copolymer                                                         105  O      A    4.2                            O.                                                                              Styrene/trimethyaminoethyl methacrylate chloride                                                          103  O      A    4.1                              (94/6) copolymer                                                            P.                                                                              Sytrene/vinyl acetate copolymer (commercial goods)                                                        123  X      C    3.1                            Q.                                                                              Styrene/vinyl pyrrolidone copolymer (commercial goods)                                                    117  X      C    3.5                            R.                                                                              Nylon (commercial goods)    110  X      C    3.4                            S.                                                                              None (control)              131  X      D    2.5                            __________________________________________________________________________

As apparent from Tables 2 and 3, all of the hair cosmetic compositioncomprising polymer latexes according to this invention were highlydepositing to hair and show preferable style-forming/retaining effectseven when using the polymer latex alone.

EXAMPLE 2

Shampoo Composition

(Formulation)

    ______________________________________                                        A     Sodium salt of polyoxyethylene(2.5)                                                                  15(%)                                                  lauryl ether sulfate                                                    B     Coconut fatty acid diethanol amide                                                                    3                                               C     Polystyrene latex A (obtained by                                                                      2                                                     Method 1 of the Synthesis Example,                                            polymer content: 20%)                                                   D     Perfume                 0.5                                             E     Colorant               slight amount                                    F     Citric acid            slight amount                                    G     Water                  balance                                          ______________________________________                                    

(Preparation Method)

The ingredient C was uniformly dispersed into the ingredient G understirring at room temperature, the ingredients A and B were added anduniformly dissolved and then the ingredients D, E and F wereincorporated into the solution to provide excellent style-forming andretaining property and favorable feeling thereby obtain a uniform andstable shampoo composition.

EXAMPLE 3

Hair Rinse Composition

(Formulation)

    ______________________________________                                        A    Distearyldimethyl ammonium chloride                                                                   2(%)                                             B    Propylene glycol        3                                                C    Styrene/vinyl acetate (99/1) copolymer                                                                1                                                     latex (obtained by Method 8 of the                                            Synthesis Example,                                                            polymer content: 20%)                                                    D    Perfume                 0.5                                              E    Colorant                slight amount                                    F    Water                   balance                                          ______________________________________                                    

(Preparation Method)

The ingredient C was uniformly dissolved in the ingredient F and heated.A heated uniform solution of the ingredients A, B and C was addedthereto under stirring followed by cooling and then ingredients D and Ewere incorporated to obtain a hair rinse composition capable ofproviding hair with an excellent style-forming/retaining property andfavorable feeling.

EXAMPLE 4

Hair Conditioner Composition

(Formulation)

    ______________________________________                                        A     Styrene/trimethylaminoethyl methacrylate                                                                1(%)                                                chloride (94/6) copolymer latex (obtained                                     by Method 8 of Synthesis Example,                                             polymer content: 20%, average                                                 particle size: 0.096 ± 0.007 μm)                                  B     Methylparaben             0.1                                           C     Ethanol                  10.0                                           D     Water                    balance                                        E     Perfume                   0.2                                           ______________________________________                                    

(Preparation Method)

The ingredient A was uniformly dispersed in the ingredient D understirring at room temperature and then ingredients B and C and E wereadded to obtain a hair conditioner capable of providing hair withexcellent style-forming/retaining property and favorable feeling.

EXAMPLE 5

Hair Set Composition

(Formulation)

    ______________________________________                                        A      Epoxy resin (obtained by Method 7                                                                     2(%)                                                  of Synthesis Example,                                                         polymer content: 20%)                                                  B      Ethanol                10                                              C      Water                  balance                                         D      Hydroxyethylcellulose   0.2                                            E      Perfume                 0.2                                            ______________________________________                                    

(Preparation Method)

The ingredient A was uniformly dispersed in the ingredient C understirring at room temperature and then ingredients B, D and E were addedto obtain a hair set composition capable of providing hair with anexcellent style-forming/retaining property and favorable feeling.

EXAMPLE 6

Hair Liquid Composition

(Formulation)

    ______________________________________                                        A      Styrene/sodium styrene sulfonate                                                                      1(%)                                                  (94/6) copolymer latex (obtained                                              by Method 8 of Synthesis Example,                                             polymer content: 20%)                                                  B      Polyoxypropylene(30) butyl ether                                                                     15.0                                            C      Ethanol                40.0                                            D      Water                  balance                                         E      Perfume                 0.3                                            ______________________________________                                    

(Preparation Method)

The ingredient A was dispersed in the ingredient D under stirring atroom temperature and then ingredients B, C and E were added and mixedwell, to obtain a hair liquid composition capable of providing hair withan excellent style-forming/retaining property and favorable feeling.

EXAMPLE 7

Hairtonic Composition

(Formulation)

    ______________________________________                                        A      Styrene/sodium styrene sulfonate                                                                      1(%)                                                  (94/6) copolymer latex (obtained                                              by Method 8 of Synthesis Example,                                             polymer content: 20%)                                                  B      PCA-Al                  0.5                                            C      Ethanol                55.0                                            D      Water                  balance                                         E      Perfume                 0.3                                            ______________________________________                                    

(Preparation Method)

The ingredient A was uniformly dispersed in the ingredient D understirring at room temperature and then ingredients B, C and E were addedand well mixed to obtain a hairtonic composition capable of providinghair with an excellent style-forming/retaining property and favorablefeeling.

EXAMPLE 8

Hair Brushing Composition

(Formulation)

    ______________________________________                                        A      Styrene/vinyl acetate (99/1)                                                                          1(%)                                                  copolymer latex (obtained by                                                  Method 8 of Synthesis Example,                                                polymer content: 20%)                                                  B      Ethanol                10.0                                            C      Polyethylene glycol 6000                                                                              3.0                                            D      Water                  balance                                         E      Perfume                 0.2                                            ______________________________________                                    

(Preparation Method)

The ingredients A-E where sufficiently dispersed in the ingredient D andstirred well to obtain a hairbrushing composition capable of providinghair with an excellent style-forming/retaining property and favorablefeeling.

EXAMPLE 9

Blow Finishing Composition

(Formulation)

    ______________________________________                                        A      Stearyltrimethyl ammonium chloride                                                                   0.4(%)                                          B      Polyethylene glycol    0.1                                             C      Perfume                0.3                                             D      Water                  balance                                         E      Polystyrene latex A (obtained by                                                                     0.5                                                    Method 1 of Synthesis Example,                                                polymer content: 20%;                                                         particle size 0.1 ± 0.01 μm)                                     ______________________________________                                    

(Preparation Method)

The ingredient E was uniformly dispersed in the ingredient D understirring and then ingredients A, B and C were added to obtain a blowfinishing composition capable of providing hair with an excellentstyle-forming/retaining property and favorable feeling.

EXAMPLE 10

Aerosol Type Hair Set Composition

(Formulation)

    ______________________________________                                        A      Styrene/trimethylaminoethyl                                                                            1(%)                                                 methacrylate chloride (94/6) copolymer                                        latex (obtained by Method 8 of                                                Synthesis Example,                                                            polymer content: 20%)                                                  B      Silicone oil             1                                             C      Perfume                  0.1                                           D      Anhydrous ethanol       balance                                        E      Furon 12                70                                             ______________________________________                                    

(Preparation Method)

Ingredients B and C were dissolved in the ingredient D and then theingredient A was added and dispersed uniformly. They were packed in aaerosol can to which a Furon gases was filled to thereby obtain anaerosol type hair set composition capable of providing excellentstyle-forming/retaining property and favorable feeling.

EXAMPLE 11

Hair Rinse Composition

(Formulation)

    ______________________________________                                        A    Distearyldimethyl ammonium chloride                                                                   2.0(%)                                           B    Stearyltrimethyl ammonium chloride                                                                    1.0                                              C    Cetyl alcohol           2.0                                              D    Liquid paraffin         1.0                                              E    Silicone oil            0.5                                              F    Propylene glycol        3.0                                              G    Styrene/vinyl acetate copolymer latex                                                                 1.0                                                   (obtained by Method 8 of Synthesis                                            Example, polymer content: 20%)                                           H    Perfume                 0.5                                              I    Colorant                slight amount                                    J    Water                   balance                                          ______________________________________                                    

EXAMPLE 12

Hair Treatment Composition

(Formulation)

    ______________________________________                                        A     Isostearyltrimethyl ammonium chloride                                                                  2.0(%)                                         B     Liquid paraffin          1.0                                            C     Collagen decomposition product                                                                         3.0                                            D     Hardened castor oil      1.0                                            E     Polyoxyethylene hardened castor oil                                                                    0.5                                                  derivative (EO60)                                                       F     Styrene/trimethylaminoethyl methacrylate                                                               1.0                                                  chloride copolymer latex (obtained by                                         Method 8 of Synthesis Example,                                                polymer content: 20%)                                                   G     Methylparaben            0.1                                            H     Ethanol                  5.0                                            I     Perfume                  0.2                                            J     Water                    balance                                        ______________________________________                                    

EXAMPLE 13

Hair Set Composition

(Formulation)

    ______________________________________                                        A     Cetostearyltrimethyl ammonium chloride                                                                  1.0(%)                                        B     Polyoxyethylene alkyl ether (EO90)                                                                      1.0                                           C     Polyoxyethylene hardened castor oil                                                                     0.5                                                 derivative (EO60)                                                       D     Cetostearyl alcohol       0.05                                          E     Styrene/potassium methacrylate                                                                          2.0                                                 (95/5) copolymer latex (obtained by                                           Method 8 of Synthesis Example,                                                polymer content: 20%)                                                   F     Ethanol                  10.0                                           G     Hydroxyethylcellulose     0.2                                           H     Perfume                   0.2                                           I     Water                    balance                                        ______________________________________                                    

EXAMPLE 14

Hair Liquid Composition

(Formulation)

    ______________________________________                                        A     Stearyltrimethyl ammonium chloride                                                                      0.05(%)                                       B     Cetanol                   0.05                                          C     Polyoxyethylene hardened castor oil                                                                     0.5                                                 derivative (EO60)                                                       D     Styrene/sodium styrene sulfonate                                                                        1                                                   (94/6) copolymer latex (obtained by                                           Method 8 of synthesis Example,                                                polymer content: 20%)                                                   E     Polyoxypropylene(30) butyl ether                                                                       15.0                                           F     Ethanol                  40.0                                           G     Perfume                   0.3                                           H     Water                    balance                                        ______________________________________                                    

EXAMPLE 15

Blow Finishing Composition

(Formulation)

    ______________________________________                                        A      Stearyltrimethyl ammonium chloride                                                                   0.4(%)                                          B      Cetyl alcohol          0.02                                            C      Polyoxyethylene alkyl ether (EO20)                                                                   0.5                                             D      Polyethylene glycol    0.1                                             E      Perfume                0.3                                             F      Polystyrene latex A (obtained by                                                                     0.5                                                    Method 1 of Synthesis Example,                                                polymer content: 20%)                                                  G      Water                  balance                                         ______________________________________                                    

EXAMPLE 16

Aerosol Type Hair Set Composition

(Formulation)

    ______________________________________                                        A     Stearyltrimethyl ammonium chloride                                                                      0.5(%)                                        B     Distearyldimethyl ammonium chloride                                                                     0.5                                           C     Styrene/trimethylaminoethyl methacrylate                                                                1.0                                                 chloride (94/6) copolymer latex                                               (obtained by Method 8 of Synthesis                                            Example, polymer content: 20%)                                          D     Silicone oil              1.0                                           E     Perfume                   0.1                                           F     Furon 12                 70                                             G     Anhydrous ethanol        balance                                        ______________________________________                                    

EXAMPLES 17-19

Hair rinse compositions shown in Table 4 were prepared according to theusual manner. All of these compositions showed more excellent hairstyle-forming/retaining effect compared with a hair rinse compositionwithout containing casein or a casein derivative, and, at the same time,they exhibited good combing performance and good feeling of the treatedhair.

                  TABLE 4                                                         ______________________________________                                                        Example                                                                       17     18       19                                            ______________________________________                                        A   Stearyl trimethyl 2 wt %   2 wt % 2 wt %                                      ammonium chloride                                                         B   Cetyl alcohol     2        2      2                                       C   Polystyrene latex A                                                                             1        1      1                                           (obtained by Method 1 of                                                      Synthesis Example,                                                            polymer content: 20%)                                                     D   Casein            1        --     --                                      E   Sodium caseinate  --       1      --                                      F   Hydrolyzed casein --       --     1                                           (average m.w. = 10,000)                                                   G   Water             balance  balance                                                                              balance                                 ______________________________________                                    

What is claimed is:
 1. A hair cosmetic composition comprising from 0.01to 10% by weight of a particulate latex polymer of water-insolublemonomers, said polymer selected from the group consisting ofpolystyrenes, copolymers of styrene with at least one vinyl monomerother than styrene, polyamides, polyurethanes, ethoxy resins andpolymethyl methacrylates, wherein said particulate polymer has a weightaverage diameter of from 0.005 to 0.2 microns a particle sizedistribution such that greater than 95% by weight of the particles havea diameter greater than 0.005 to 0.2 microns and wherein saidparticulate polymer has a glass transition temperature greater than 300°K.
 2. The hair cosmetic composition of claim 1, wherein said vinylmonomer is selected from the group consisting of ethylenicallyunsaturated monomers, aromatic vinyl monomers, acrylic esters havingC₁₋₂₀ carbon atoms in the alkyl group, C₁₋₂₀ vinyl ethers, C₁₋₂₀ vinylketones, vinyl cyano monomers, halogenated vinyl monomers and conjugatedaliphatic dienes.
 3. The hair cosmetic composition of claim 1, whereinsaid vinyl monomer is selected from the group consisting of ethylene,propylene, isobutene, 1-butene, α-methylstyrene, vinyl toluene,halogenated styrene, divinyl benzene, ethyl acrylate, butyl acrylate,2-ethylhexyl acrylate, methyl methacrylate, butyl methacrylate, laurylmethacrylate, vinyl acetate, vinyl propionate, ethyl vinyl ether, butylvinyl ether, methyl vinyl ketone, ethyl vinyl ketone, acrylonitrile,methacrylonitrile, vinyl chloride, vinyl bromide, vinylidene chloride,vinylidene bromide, 1,3-butadiene and 2-methyl-1,3-butadiene.
 4. Thehair cosmetic composition of claim 1, wherein the weight averagediameter of said particulate polymer is from 0.01 to 1.0 microns.
 5. Thehair cosmetic composition of claim 1, wherein said particulate polymerlatex is selected from the group consisting of polystyrene,polyvinylacetate, polydivinylbenzene, polymethylmethacrylate,poly-n-butylacrylate, poly-n-butylmethacrylate,poly-2-ethylhexylmethacrylate, 6,12-nylon, polyurethanes, epoxy resins,styrene/vinyl acetate copolymers andstyrene/trimethylaminoethylmethacrylate chloride copolymers.
 6. The haircosmetic composition of claim 1, further comprising ethanol or siliconeoil.
 7. The hair cosmetic composition of claim 1, further comprising asurface active agent.
 8. A hair cosmetic composition comprising:(A) from0.01 to 20% by weight of at least one long chain alkyl quaternaryammonium salt having the formula: ##STR3## wherein one or two of R₁, R₂,R₃ and R₄ is a linear or branched C₈₋₂₄ alkyl group and the remaining Rgroups are, independently, a C₁₋₃ alkyl or hydroxy alkyl group or abenzyl group, and X is a halogen atom or a C₁₋₂ alkyl sulfate group; (B)from 0.1 to 30% by weight of oils and fats, and (C) from 00.1 to 10% byweight of a particulate polymer latex selected from the group consistingof polystyrenes, copolymers of styrene and at least one vinyl monomerother than styrene, polyamides, polyurethanes, epoxy resins andpolymethylmethacrylates, wherein said particulate polymer has a weightaverage diameter of from 0.005 to 0.2 microns a particle sizedistribution such that greater than 95% by weight of the polymerparticles are in the range of from 0.005 to 0.2 microns in diameter andsaid particulate polymer has a glass transition temperature greater than300° K., and (D) ethanol or silicone oil.